Published: février 8, 2023

SNF’s Oil & Gas Division presents:

POLYMER ENHANCED OIL RECOVERY: THE BEST OF BOTH WORLDS! as published in the Exploration & Production section of the Winter 2023 OG Innovation Magazine.

The full article can be read below:

Polymer Enhanced Oil Recovery:
The Best of Both Worlds!

Background

What if there was a magic bullet that reduces your carbon footprint whilst economically allowing you to add more recoverable reserves to your portfolio? You would take it, right? But that can’t possibly exist! Or can it? Surprisingly, polymer Enhanced Oil Recovery (EOR) can not only do this in theory but is actually a globally deployed technology in over 350 projects that has shown to be highly effective in sustainably recovering more oil. Whilst more common onshore, what have been the barriers to implementation in the offshore environment? Higher risk perception, cost, retrofitting limitations and increased complexity have all been contributing factors, but with more and more offshore projects now being sanctioned and successfully executed there is perhaps no better time to evaluate polymer EOR. For the North Sea in particular, the energy transition and the requirement to reduce all carbon emissions to zero by 2050 (Net Zero) will require operators to maximise their recoverable reserves whilst doing so within a carbon-neutral environment.

Concept

So, what makes polymer flooding so attractive? Globally, 60% of all oilfields are currently using water-flooding as a way to maintain reservoir pressure but this only recovers 20-40% of the oil in the reservoir. The lower viscosity of the water leads to poor sweep leaving most of the oil within the reservoir. Additionally, once this injected water breaks through at the production wells, a rapid increase in water-cut is often observed with the resulting production issues that follow (scale, separation etc) requiring additional chemical treatment. In the North Sea, this water must be treated before being reinjected at great cost to the operator. Adding polymer to the injected water increases the viscosity of the water phase, reducing the mobility of the water resulting in higher recovery factors.

Figure 1 (left) highlights the increase in oil recovery for water-flooding vs polymer EOR for over the same project lifetime (15 years). Over this period polymer flooding recovered around twice the number of barrels as water-flooding alone. Another way to view this data is that in order to recover the same amount of oil, it takes twice as long under water-flood.

Just as important to the improved oil recovery factors is the reduction in the amount of water being injected, produced and treated. The majority of associated carbon emissions from oil production can be directly attributed to the energy required to run the water-flood. Therefore, it stands to reason that if you can reduce the overall amount of water that you have to handle, you will reduce the carbon footprint of your operation.

Figure 2 highlights the relationship between water cut and the resulting carbon intensity to produce a single barrel of oil. As the water cut rises to 80% and above, the carbon intensity begins to rise exponentially. With an ageing basin such as the North Sea, reducing the water cut would have a substantial benefit to the future of the industry there. Water injection requires high amounts of energy to inject the water, often from burning produced gas in gas turbines which contributes significantly to a company’s emission calculations. Reducing the amount of produced water will decrease the amount of lifting energy required to produce a barrel of oil, often via electrical submersible pumps (ESP) or gas lift operations, further reducing carbon emissions. Figure 1 (right) shows that when adjusted to the same oil recovery values (~32,000,000bbls), the amount of CO2 emitted is around half that for the polymer EOR project than water-flooding.

 

Figure 3 shows an example of a full carbon emissions calculation of a water-flood vs. polymer flood. The carbon intensity to recover 1 barrel of oil during water-flood was calculated as being 26kg CO2/bbl in this example. The polymer flood calculation shows a slight increase in energy usage for the running of the polymer injection unit (PIU) and manufacture/transportation of the chemicals, but these are almost negligible compared to the energy savings due to the reduction water handling. Overall, the carbon intensity is reduced from 26 to 7 kg CO2/bbl of oil produced, a saving of ~70%. This magnitude of reduction in carbon intensity falls within the average values of the polymer flood operations that SNF have implemented and studied in the field as demonstrated in Figure 4.

Supply Chain

In order to maximise the environmental benefit, it is imperative to ensure that all steps are being taken to minimise the carbon footprint contributions from the manufacturing and transport logistics. SNF not only constantly adapt and improve our formulations and processes to ensure that the least amount of energy is consumed during manufacture, but we also strive to reduce the carbon emissions associated with transportation. This is demonstrated by our investment in our manufacturing plant in the Teesside area, purpose-built to serve the future needs of the North Sea. Previously our products were manufactured in France and transported by road to Aberdeen for shipping to the offshore installation. This shorter supply route (~460km vs. ~1900km) represents greater than 4x reduction in the carbon footprint in transport alone (80kg CO2/ton vs. 325kg CO2/ton). Planned refinement of the supply route via rail or sea transportation to suit the chemical requirements of the North Sea will reduce emissions further.

Managing Risk

As mentioned above, many offshore EOR projects have been ruled out in the past following initial evaluation due to many factors including injectivity, product quality, asset retrofit, produced water issues and economics. SNF have continued to innovate in this area in order to minimise these risks. For example, by dewatering our liquid emulsion polymers, commonly used offshore for ease of deployment, the volumes required have been drastically reduced meaning better product stability (less water) and a reduction in the size of the required storage facilities on the platform or FPSO due to lower volumes of bulk emulsion being required. Advances in emulsion technology mean that good injectivity is routinely achieved. On the economics side, new research from Heriot-Watt University looking at the way in which polymer works at the pore scale to produce oil, demonstrates that relatively low dosages of polymer can achieve highly profitable results even in heavy oil reservoirs. So, projects previously ruled out due to unfavourable or marginal Net Present Value (NPV) calculations due to high polymer loading may now be greatly beneficial. In fact, it has been calculated that polymer EOR adds only $4-6 per incremental barrel to the overall economics of a water-flood project. This is no more apparent than with Ithaca in the Captain field where wells at the limit of their economic benefit due to extremely high water-cuts are now some of the most profitable on the asset due entirely to the polymer flood project. Finally, back-produced polymer has always been a topic of great concern to operators, fearing process upsets and poor water quality for reinjection. Advances in this area have also been made in recent years with bespoke products for polymer-containing systems being developed to enable better separation and aid water clean-up.

In summary, the time has never been more primed to evaluate (or re-evaluate) polymer EOR for North Sea deployment. Reducing carbon emissions and maximising production will ensure the longevity of the North Sea oil and gas industry to enable us meet the changing energy demands of the future. In essence, polymer Enhanced Oil Recovery gives us the best of both worlds – sustainable, profitable oil production!

If you would like to know more about the topics discussed in this article, or would like to know more about SNF’s solutions, please contact them at:

SNF
www.snf.com
eor@snf.com

Contactez SNF dès aujourd'hui!


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MODIFICATEURS DE RHÉOLOGIE 

Additifs fluidifiants par cisaillement qui contrôlent les propriétés rhéologiques et d'écoulement des fluides de forage afin d'améliorer le transport des déblais, la suspension, le nettoyage du puits et la stabilité du forage.

AGENTS VISCOSIFIANTS (WBM ET OBM) 

Large gamme de PHPA à haut poids moléculaire pour les fluides de forage à base d’eau (WBM), ainsi que de viscosifiants OBM à base de latex, utilisables depuis le tubage de surface jusqu’aux environnements HPHT et dans des saumures allant jusqu’à saturation.

CONTRÔLE DES PERTES DE FLUIDE 

Polymères linéaires et structurés offrant d’excellentes performances en contrôle des pertes de fluide, contribuant à la maîtrise de la filtration et à la stabilité du puits depuis le tubage de surface jusqu’aux profondeurs HPHT et dans des environnements à salinité élevée.

INHIBITEURS DE SCHISTES 

Polyamines liquides ou solides, à haute performance et respectueuses de l’environnement, conçues pour prévenir l’instabilité et le gonflement des formations schisteuses sensibles.

DISPERSANTS ET FLUIDIFIANTS 

Les dispersants à base de polyacrylates de faible poids moléculaire réduisent la viscosité des boues et contribuent au contrôle de la force du gel.

EXTENSEURS DE BENTONITE 

Extenseurs polymériques fortement anioniques, disponibles dans une large gamme de poids moléculaires, permettant d’augmenter la viscosité des systèmes de boues non dispersées.

MATERIAUX DE PERTE DE CIRCULATION (LCM) 

Les polymères superabsorbants utilisés comme LCM agissent en colmatant et en comblant les zones de pertes partielles ou totales lors des opérations de forage, aussi bien en eau douce qu’en environnements fortement salins.

LUBRIFIANTS 

Produits spécialisés conçus pour assurer une lubrification durable et une protection contre l'usure des trépans, des tiges de forage et des outils de fond de puits en réduisant le frottement des fluides de forage et de complétion.

AGENTS ANTIMOUSSE 

Additifs qui préviennent et éliminent la formation de mousse afin de maintenir les propriétés du fluide de forage pour des opérations de forage rapides et sûres.

CONTROLE DES PERTES DE FLUIDE 

Additifs de contrôle des pertes de fluide pour la cimentation, capables de tolérer toutes les salinités et des températures de fond de puits allant jusqu’à 400 °F (204 °C). Ils sont compatibles avec tous les types de ciments utilisés dans les puits pétroliers et gaziers.

CONTROLE DE LA MIGRATION DES GAZ 

Additifs permettant de contrôler la migration des gaz et de prévenir une résistance mécanique insuffisante ou une mauvaise adhérence du ciment, même à faibles dosages.

RETARDATEURS 

Homopolymères linéaires, polyacrylates et copolymères sulfonés, disponibles dans différentes gammes de poids moléculaires, permettant de contrôler le temps de prise du ciment sur plusieurs heures.

DISPERSANTS 

Dispersants à base de polyacrylates de faible poids moléculaire améliorant les propriétés d’écoulement des coulis de ciment en réduisant la viscosité et en empêchant l’agglomération des particules, tout en contribuant au contrôle de la force du gel.

ADDITIFS DE SUSPENSION 

Ces produits sont conçus pour améliorer la capacité de suspension des coulis de ciment en maintenant le ciment et les autres particules solides dispersés dans la phase liquide. Les additifs de suspension empêchent la sédimentation des solides et réduisent la quantité de fluide libre, assurant ainsi une mise en place correcte du ciment.

FLUIDES D'ESPACEMENT ET FLUIDES DE PACKER 

Ces fluides spécialisés sont conçus avec des propriétés spécifiques pour déplacer efficacement le fluide de forage et prévenir la contamination du ciment, permettant ainsi une mise en place optimale du ciment.

MATERIAUX DE PERTE DE CIRCULATION 

Les polymères superabsorbants utilisés comme LCM permettent de bloquer et de combler les zones de pertes partielles ou totales lors des opérations de cimentation.

AGENTS ANTIMOUSSE 

Des additifs qui préviennent et éliminent la formation de mousse permettent de maintenir les propriétés de la boue de ciment pour un meilleur placement du ciment et une meilleure isolation des zones. Les agents antimousse garantissent une densité de boue précise, une faible porosité, une résistance élevée et un minimum de défauts dans la gaine de ciment.

STABILISATEURS DE PUITS 

Polymères linéaires et structurés assurant une stabilisation efficace des puits sensibles grâce à la formation d’un gâteau de filtration mince et homogène, agissant comme une barrière protectrice à l’interface avec la formation.

Friction Reducers (FRs / HVFRs) 

SNF’s high-performance friction reducers and HVFRs lower pumping pressures, enhance fluid flow, and improve operational efficiency—reducing total water and energy consumption during hydraulic fracturing.

Linear / Crosslinked Gels 

Delivering consistent viscosity and superior proppant transport. SNF’s linear and crosslinked gels are formulated for excellent stability, controlled cleanup, and performance across a wide range of formations.

Permanent Clay Stabilizers 

Prevent formation damage and maintain long-term well productivity. Our permanent polymer-based stabilizers effectively minimize clay swelling and migration.

Scale Inhibitors 

Protect wellbore and surface equipment from mineral scaling. SNF’s scale inhibitors extend asset life and preserve production efficiency throughout stimulation and flowback.

Acid Gelling Aids 

Enhance acid placement and control leak-off during matrix stimulation. SNF's acid gelling aids improve fluid performance and overall treatment effectiveness.

Coiled Tubing Friction Reducers 

Achieve smoother, more efficient coiled tubing operations. These friction reducers lower surface pressures and optimize fluid flow during continuous pumping applications.

Pipeline / Disposal Well Drag Reducers 

Increase throughput and reduce pumping costs in pipeline and disposal well systems. SNF's drag reducers maintain stability and efficiency over long distances.

Surfactants 

Promote improved hydrocarbon recovery and flowback. SNF’s surfactants reduce interfacial tension and enhance fluid compatibility across a wide range of conditions.

Biocides 

Control bacterial growth that can lead to corrosion, souring, or plugging. SNF’s regulated biocide solutions maintain fluid integrity and equipment reliability.

pH Adjusters 

Optimize crosslinker and breaker efficiency through precise pH control. SNF’s adjusters ensure consistent fluid chemistry and predictable performance.

Corrosion Inhibitors 

Extend the life of your tubulars and equipment. SNF's corrosion inhibitors provide strong protection against the harsh environments of stimulation operations.

Breakers 

Deliver clean, controlled gel breakdown for improved formation permeability. SNF’s breakers ensure complete cleanup and maximum flow restoration.

Oxygen Scavengers 

Protect polymers and metal assets from oxidation and corrosion. FLOJET™ O2 delivers fast, dependable oxygen removal for safer, longer-lasting fluid systems.

RHEOLOGY MODIFIERS 

Shear-thinning additives that control the rheological and flow properties of drilling fluids to improve cuttings transport, suspension, hole cleaning, and wellbore stability.

VISCOSIFIERS (WBM and OBM) 

Wide range of high molecular weight PHPA for WBM and latex-based OBM viscosifiers for use in drilling surface casing to HPTH depths and up to saturated salts.

FLUID LOSS CONTROL 

Linear and structured polymers that are excellent fluid loss control additives for filtration control and wellbore stability from surface casing to HPTH depths and up to saturated salts.

SHALE INHIBITORS 

High-performance and environmentally friendly liquid or dry polyamines that prevent instability and swelling of sensitive shale formations.

WELLBORE STABILIZERS 

Linear and structured polymers that are excellent stabilizers of sensitive wellbore by creating a thin and uniform filter cake that works as a barrier on the formation face.

Dispersants & Thinners 

Low-MW polyacrylates dispersants reduce mud viscosity and help control gel strength.

BENTONITE EXTENDERS 

High anionic with a wide range of molecular weights polymeric extenders helps increase viscosity in non-dispersed mud systems

LOST CIRCULATION MATERIALS (LCM) 

Superabsorbent polymers LCM work by blocking and filling partial and total loss zones during drilling operations for freshwater and high salinity environments

LUBRICANTS 

Specialized products designed to provide long-lasting lubrication and wear protection for drill bit, drill pipe, and downhole tools by reducing the friction of drilling and completion fluids.

DEFOAMERS 

Additives that prevent and break down foam formation to maintain drilling fluid properties for fast and safe drilling operations.

FLUID LOSS CONTROL 

Cement fluid loss control additives that can tolerate all salinities and up to 400°F (204°C) downhole temperature.  Also, work for all types of cements used in the oil and gas wells.

GAS MITIGATION CONTROL 

Additives that can control gas migration and prevent poor set strength and inadequate cement bond with a small dosage.

RETARDERS 

Linear homopolymers, polyacrylates, and sulfonated copolymers with a variety of Mw ranges assist in controlling the cement setting time to several hours.

DISPERSANTS 

Low-MW polyacrylates dispersants that improve the flow properties of cement slurries by reducing viscosity and preventing particle clumping, and help control gel strength.

SUSPENSION ADDITIVES 

Products engineered to improve the suspension capability of cement slurry by keeping cement and other solid particles dispersed in the liquid phase. Suspension additives prevent solids sag and reduce free fluid for proper cement placement.

SPACERS & PACKER FLUIDS 

Specialized fluids designed with specific properties to efficiently displace the drilling fluid and prevent cement contamination to allow optimal cement placement.

LOST CIRCULATION MATERIALS (LCM) 

Superabsorbent polymers LCM work by blocking and filling partial and total loss zones during cementing operations.

DEFOAMERS 

Additives that prevent and break down foam formation to maintain cement slurry properties for better cement placement and zonal isolation. Defoamers ensure accurate slurry density, low porosity, high strength, and minimal defects in the cement sheath.

Réducteurs de friction (FR / HVFR) 

Les réducteurs de friction haute performance et les technologies HVFR de SNF permettent de réduire les pressions de pompage, d’améliorer l’écoulement des fluides et d’optimiser l’efficacité opérationnelle. Ils contribuent ainsi à réduire la consommation globale d’eau et d’énergie lors des opérations de fracturation hydraulique.

Gels linéaires / gels réticulés 

Offrant une viscosité maîtrisée et un transport optimal du proppant, les gels linéaires et réticulés de SNF sont formulés pour garantir une excellente stabilité, un nettoyage contrôlé et des performances élevées sur une large gamme de formations.

Stabilisants d’argiles permanents 

Ces solutions permettent de prévenir les dommages à la formation et de préserver durablement  la productivité des puits. Les stabilisants permanents à base de polymères de SNF réduisent efficacement le gonflement et la migration des argiles.

Inhibiteurs de tartre 

Les inhibiteurs de tartre de SNF protègent les équipements de fond et de surface contre la formation de dépôts minéraux. Ils contribuent à prolonger la durée de vie des actifs et à préserver l’efficacité de la production tout au long des phases de stimulation et de flowback.

Agents de gélification pour acides 

Les agents de gélification pour acides de SNF améliorent le placement de l’acide et le contrôle des pertes de fluide lors des opérations de stimulation matricielle. Ils renforcent les performances des fluides et optimisent l’efficacité globale des traitements.

Réducteurs de friction pour coiled tubing 

Ces réducteurs de friction sont conçus pour rendre les opérations de coiled tubing plus fluides et plus efficaces. Ils permettent de réduire les pressions en surface et d’optimiser l’écoulement des fluides lors des applications de pompage en continu.

MINING FLOCCULANTS 

SNF’s FLOPAM™ product line has been specifically designed to treat Oil Sands tailings streams. It can be used in thickening and end-of-pipe applications for rapid, clean water recovery and solid consolidation

Réducteurs de traînée pour pipelines et puits de réinjection 

Les réducteurs de traînée de SNF permettent d’augmenter les débits tout en réduisant les coûts de pompage dans les systèmes de pipelines et les puits de réinjection. Ils garantissent une stabilité et une efficacité durables, même sur de longues distances.

MINING COAGULANTS 

SNF’s FLOQUAT™ product range is designed to help with water quality when straight flocculation is not enough to achieve needed results.

Tensioactifs 

Les tensioactifs de SNF favorisent une optimisée des hydrocarbures et un flowback plus efficace. En réduisant la tension interfaciale, ils améliorent la compatibilité des fluides sur une large gamme de conditions opératoires.

Biocides 

Les biocides de SNF permettent de contrôler efficacement la prolifération bactérienne susceptible de provoquer la corrosion, la sulfuration ou l’obstruction des systèmes. Conformes aux exigences réglementaires, ces solutions préservent l’intégrité des fluides et assurent la fiabilité durable des équipements.

FILTRATION AND MECHANICAL DEWATERING AIDS 

SNF’s FLOPAM™ product line is engineered for vacuum filtration and centrifuge applications, helping operators reduce cycle times, achieve drier cakes, and produce cleaner filtrate or centrate for improved process efficiency.

Ajusteurs de pH 

Les ajusteurs de pH de SNF assurent un contrôle précis du pH afin d’optimiser l’efficacité des agents de réticulation et des breakers. Ils contribuent à une chimie des fluides constante et des performances fiables et prévisibles sur le terrain.

Inhibiteurs de corrosion 

Les inhibiteurs de corrosion de SNF contribuent à prolonger la durée de vie des tubulaires et des équipements en offrant une protection renforcée contre les environnements sévères rencontrés lors des opérations de stimulation.

SAGD FLOCCULANTS AND COAGULANTS 

SNF’s HYPERFLOC™ product line features advanced chemistries tailored for warm and hot lime softening in SAGD operations. These high-temperature-tolerant polymers deliver lower dosage requirements while maintaining critical boiler water treatment KPIs for consistent and reliable performance.

Breakers (agents de rupture) 

Les breakers de SNF assurent une rupture propre et contrôlée des gelsafin d’améliorer la perméabilité de la formation. Ils garantissent un nettoyage efficace et une restauration optimale des débits.

Piégeurs d’oxygène 

Les piégeurs d’oxygène protègent les polymères et les équipements métalliques contre l’oxydation et la corrosion. FLOJET™ O2 assure une élimination rapide et fiable de l’oxygène, contribuant à des systèmes de fluides plus sûrs et plus durables.

SAGD FILTER AIDS AND ANTIFOULANTS 

SNF’s HYPERFLOC™ product line is engineered to withstand the high temperatures of SAGD processes, helping minimize plant downtime caused by backflushing or cleaning cycles.

DRAG REDUCERS 

SNF’s FLOJET™ DR drag reducers are high-performance emulsion polymers engineered to enhance flow assurance and pipeline efficiency by significantly reducing frictional pressure losses, pumping energy requirements, and fluid degradation across a broad range of water conditions.

DUST SUPPRESSION 

SNF’s FLOSET™ RDC product line offers chloride-free, environmentally responsible dust suppression solutions specifically formulated for haul roads, tailings areas, and administrative sites, helping improve air quality and site safety.

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